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Malaysian Journal of Chemistry, 2017, Vol. 19(2), 82 – 98

Remediation of Cationic Dye Simulated Wastewater Using Photolysis: Parametric and Kinetic Studies

Collin G. Joseph1*, Yun Hin Taufiq-Yap2, L. Elilarasi and Vigneswar Krishnan1
1Sonophotochemistry Research Group, Faculty of Science and Natural Resources, Universiti Malaysia Sabah, 88400 Kota Kinabalu, Sabah
2Centre of Excellence for Catalysis Science and Technology, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang

 *Corresponding author: (e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.) 

Received: May 2017; Accepted: July 2017

ABSTRACT

In this study, the photodegradation of methylene blue (MB) simulated wastewater was investigated using three types of UV lamps emitting UV-A, UV-B, UV-C and a solar lamp emitting solar irradiation, as the source of light to enable the destruction of MB molecules by photochemical reactions. From the experimental data, UV-C irradiation proved to be the most effective irradiation light source that resulted in 96.7% degradation of MB after 5 h of irradiation, while solar irradiation treatment on the simulated dye wastewater degraded 29.6% of MB after 5 h of exposure and proved to be an encouraging option for this treatment as sunlight is a renewable, green energy source. COD analysis percentage of 83.3% achieved after 60 min proved the effectiveness of using this treatment option. Kinetic studies showed that all experiments fulfilled first-order kinetics (the correlation coefficient ranged between r=0.7495 to 0.998) for MB photo degradation.

Key words: Dye; photolysis; pretreatment; methylene blue; photodegradation; biochemical degradation; textile

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